SUSTAINABLE BROMINATION OF ORGANIC COMPOUNDS
DOI:
https://doi.org/10.36676/urr.v12.i2.1592Keywords:
ORGANIC COMPOUNDS, green chemistryAbstract
Bromination is one of the most important transformations in organic synthesis and can be carried out using bromine and many other bromo compounds. Use of molecular bromine in organic synthesis is well-known. However, due to the hazardous nature of bromine, enormous growth has been witnessed in the past several decades for the development of solid bromine carriers. This paper outlines the sustainable bromination of organic compounds focuses on carrying out bromination reactions in an environmentally friendly, energy-efficient, and less hazardous way, aligning with the principles of green chemistry.
References
(1) Herrmann, H.; Majdik, Z.; Ervens, B.; Weise, D. Halogen Production from Aqueous Tropospheric Particles. Chemosphere 2003, 52, 485−502.
(2) Rasmussen, R. A.; Khalil, M. A. K.; Dalluge, R. W.; Penkett, S. A.; Jones, B. A Somewhat Forgotten Physicist. Science 1982, 215, 655− 656.
(3) Butler, A.; Sandy, M. Mechanistic Considerations of Halogenating Enzymes. Nature 2009, 460, 848. (4) Vaillancourt, F. H.; Yeh, E.; Vosburg, D. A.; Garneau-Tsodikova, S.; Walsh, C. T. Nature’s Inventory of Halogenation Catalysts: Oxidative Strategies Predominate. Chem. Rev. 2006, 106, 3364−3378.
(5) Ioffe, D.; Kampf, A. Bromine, Organic Compounds. Kirk-Othmer Encyclopedia of Chemical Technology, 5th ed.; John Wiley & Sons, Inc.: New York, 2004, Vol. 4, pp 340−345.
(6) Turner, D. L. Determination of Brominated Vegetable Oil Concentrations in Soft Drinks using a Specific Ion Electrode. J. Food Sci. 1972, 37, 791−792.
(7) Laskowski, D. A. Physical And Chemical Properties of Pyrethroids. Rev. Environ. Contam. Toxicol. 2002, 174, 49−170.
(8) Green, J. Mechanisms for Flame Retardancy And Smoke Suppression -A Review. J. Fire Sci. 1996, 14, 426−442.
(9) Gribble, G. W. The Diversity of Naturally Occurring Organobromine Compounds. Chem. Soc. Rev. 1999, 28, 335−346.
(10) Decanio, S. J.; Norman, C. S. Economics Of The “Critical Use” of Methyl Bromide under The Montreal Protocol. Contemp. Econ. Policy 2005, 23, 376−393.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Universal Research Reports
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
